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Mar 2013

Volume 42, Issue 1, Articles (01xxxx)

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IUPAC-NIST Solubility Data Series. 94. Rare Earth Metal Iodides and Bromides in Water and Aqueous Systems. Part 2. Bromides

Tomasz Mioduski, Cezary Gumiński, Dewen Zeng, and Heidelore Voigt

J. Phys. Chem. Ref. Data 42, 013101 (2013); http://dx.doi.org/10.1063/1.4766752 (35 pages)

Online Publication Date: 14 January 2013

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This work presents solubility data for rare earth metal bromides in water and in aqueous ternary systems. Compilations of all available experimental data are introduced for each rare earth metal bromide with a corresponding critical evaluation. Every such evaluation contains a collection of all solubility results in water, a selection of suggested solubility data and a brief discussion of the multicomponent systems. Because the ternary systems were almost never studied more than once, no critical evaluations of such data were possible. Only simple bromides (no complexes) are treated as the input substances in this work. The literature has been covered through the end of 2011.
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64.75.Bc Solubility
01.30.Kj Handbooks, dictionaries, tables, and data compilations

IUPAC-NIST Solubility Data Series. 97. Solubility of Higher Acetylenes and Triple Bonded Derivatives

Peter G. T. Fogg, Editor, Contributor, Evaluator and Adam Skrzecz, Contributor

J. Phys. Chem. Ref. Data 42, 013102 (2013); http://dx.doi.org/10.1063/1.4772390 (66 pages)

Online Publication Date: 28 February 2013

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Solubility of Ethyne in Liquids was published in 2001 as Vol. 76 of the IUPAC-NIST Solubility Data Series. The current work extends the coverage to the solubility in liquids of higher gaseous and liquid acetylenes and to derivatives that contain a triple carbon-carbon bond. Predictive methods for estimating solubilities in water are summarised and usually give values to within an order of magnitude. The literature has been surveyed to the end of 2010.
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64.75.Bc Solubility
33.15.Fm Bond strengths, dissociation energies

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 1. Binary Solvent Mixtures

William E. Acree, Jr.

J. Phys. Chem. Ref. Data 42, 013103 (2013); http://dx.doi.org/10.1063/1.4772674 (188 pages) | Cited 1 time

Online Publication Date: 28 February 2013

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This work updates Vols. 54, 58, and 59 in the IUPAC Solubility Data Series and presents solubility data for polycyclic aromatic hydrocarbon solutes dissolved in binary organic solvent mixtures. Published solubility data for anthracene, naphthalene, phenanthrene, phenothiazine, and pyrene that appeared in the primary literature between 1995 to the end of 2011 are compiled and critically evaluated. Experimental solubility data for 360 different solute-binary solvent systems are included in the volume. Solubility data published prior to 1995 were contained in three earlier volumes (Vols. 54, 58, and 59) and are not repeated in this volume.
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64.75.Bc Solubility
01.30.Kj Handbooks, dictionaries, tables, and data compilations

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 2. Ternary Solvent Mixtures

William E. Acree, Jr.

J. Phys. Chem. Ref. Data 42, 013104 (2013); http://dx.doi.org/10.1063/1.4773073 (84 pages) | Cited 1 time

Online Publication Date: 28 February 2013

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This work updates Vols. 54, 58, and 59 in the IUPAC Solubility Data Series and presents solubility data for polycyclic aromatic hydrocarbon solutes dissolved in ternary organic solvent mixtures. Published solubility data for anthracene, phenanthrene, and pyrene that appeared in the primary literature between 1995 to the end of 2011 are compiled and critically evaluated. Experimental solubility data for 119 different solute-ternary solvent systems are included in the volume. Solubility data published prior to 1995 were contained in three earlier volumes (Vols. 54, 58, and 59) and are not repeated here.
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64.75.Bc Solubility
01.30.Kj Handbooks, dictionaries, tables, and data compilations

IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures—Revised and Updated. Part 3. Neat Organic Solvents

William E. Acree, Jr.

J. Phys. Chem. Ref. Data 42, 013105 (2013); http://dx.doi.org/10.1063/1.4775402 (223 pages)

Online Publication Date: 4 March 2013

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This work updates Vols. 54, 58, and 59 in the IUPAC Solubility Data Series and presents solubility data for polycyclic aromatic hydrocarbon solutes dissolved in neat organic solvents. Published solubility data for acenaphthene, anthracene, biphenyl, carbazole, dibenzofuran, dibenzothiophene, fluoranthene, fluorene, naphthalene, phenanthrene, phenothiazine, pyrene, thianthrene, and xanthene that appeared in the primary literature from 1995 to the end of 2011 are compiled and critically evaluated. Experimental solubility data for more than 550 different solute-organic solvent systems are included. Solubility data published prior to 1995 were contained in three earlier volumes (Vols. 54, 58, and 59) and are not repeated in this volume.
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64.75.Bc Solubility
64.75.Ef Mixing
01.30.Kj Handbooks, dictionaries, tables, and data compilations

Reference Correlation of the Thermal Conductivity of n-Hexane from the Triple Point to 600 K and up to 500 MPa

M. J. Assael, S. K. Mylona, Ch. A. Tsiglifisi, M. L. Huber, and R. A. Perkins

J. Phys. Chem. Ref. Data 42, 013106 (2013); http://dx.doi.org/10.1063/1.4793335 (8 pages) | Cited 1 time

Online Publication Date: 11 March 2013

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This paper contains new, representative reference equations for the thermal conductivity of n-hexane. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory whenever possible. In the case of the dilute-gas thermal conductivity, a theoretically based correlation was adopted in order to extend the temperature range of the experimental data. Moreover, in the critical region, the experimentally observed enhancement of the thermal conductivity is well represented by theoretically based equations containing just one adjustable parameter. The correlations are applicable for the temperature range from the triple point to 600 K and pressures up to 500 MPa. The overall uncertainty (considered to be estimates of a combined expanded uncertainty with a coverage factor of 2) of the proposed correlation is estimated, for pressures less than 500 MPa and temperatures less than 600 K, to be less than 6%.
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51.20.+d Viscosity, diffusion, and thermal conductivity
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