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Oct 1972

Volume 1, Issue 4, pp. 841-1114


The Surface Tension of Pure Liquid Compounds

Joseph J. Jasper

J. Phys. Chem. Ref. Data 1, 841 (1972); http://dx.doi.org/10.1063/1.3253106 (170 pages) | Cited 5 times

Online Publication Date: 29 October 2009

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The surface tension tables presented herein are the result of a literature survey, evaluation, and compilation of data of some 2200 pure liquid compounds, 226 of which were reported for a single temperature. These are arranged with related compounds in the increasing order of their molecular weights. As far as possible the method of measurement, nature of atmosphere to which the liquid was exposed during measurements, and the estimated accuracy are given for each liquid. The tabulated values were calculated from the derived results of directly measured quantities reported in the literature of many countries from about 1874 to 1969. Preliminary plots of the experimentally measured quantities indicated that the surface tensions of the liquid compounds are linear functions of the temperature over the reported operational range. The principle of least squares was applied to experimental surface tension values to establish the regression curves and their equations. The constants of the equations (slope and intercept), together with the standard deviations are given for each compound. The selection factors establishing criteria of quality of surface tension data are discussed. These include (a) method of measurement, (b) purity of compound, (c) quality of apparatus and assembly, (d) experimental procedure (experimentation), (e) reliability of measurements (most probable values), (f) experience of investigator, and (g) availability of data. There are 274 references listed alphabetically.
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68.03.Cd Surface tension and related phenomena

Microwave Spectra of Molecules of Astrophysical Interest: 1. Formaldehyde, Formamide, and Thioformaldehyde

Donald R Johnson, Frank J. Lovas, and William H. Kirchhoff

J. Phys. Chem. Ref. Data 1, 1011 (1972); http://dx.doi.org/10.1063/1.3253107 (36 pages)

Online Publication Date: 29 October 2009

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The available data on the microwave spectra of formaldehyde, formamide, and thioformaldehyde are critically reviewed for information applicable to radio astronomy. Molecular data such as rotational constants, centrifugal distortion parameters, dipole moments, hyperfine coupling constants, and structural parameters are tabulated. Observed rotational transitions are presented for the astronomically interesting isotopic forms of these molecules when available. Detailed centrifugal distortion calculations have been carried out for the most abundant isotopic forms of these molecules, namely, H212C16O, H213C16O, 14NH212CH16O, and H212C32S. Transitions have been predicted and tabulated for the frequency ranges 1 MHz to 300 GHz for H212C16O,100 MHz to 300 GHz for H213C16O,500 MHz to 180 GHz for 14NH212CH16O,100 MHz to 300 GHz for H212C32S. All predicted transitions include 95 percent confidence limits; measured transition error limits have been reproduced from the original literature. References are given for all data included.
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33.20.Bx Radio-frequency and microwave spectra
95.30.Ft Molecular and chemical processes and interactions
98.38.Bn Atomic, molecular, chemical, and grain processes

Osmotic Coefficients and Mean Activity Coefficients of Uni‐univalent Electrolytes in Water at 25°C

Walter J. Hamer and Yung‐Chi Wu

J. Phys. Chem. Ref. Data 1, 1047 (1972); http://dx.doi.org/10.1063/1.3253108 (54 pages) | Cited 8 times

Online Publication Date: 29 October 2009

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This paper gives values for the osmotic coefficients and mean activity coefficients of uni‐univalent electrolytes in aqueous solutions at 25 °C. The values are expressed on the molality or weight basis. The data available in the literature have been corrected to the presently accepted scales of atomic weights (1969) and temperature (IPST 1968) and, where necessary, to the absolute electrical units of 1969 and the fundamental constants of 1963. The selected values of osmotic coefficients and mean activity coefficients for individual electrolytes have been made internally consistent thermodynamically. In some cases estimated values are given; in other cases, references only are given when the data are sparse or unsuited to critical evaluation. Values of the osmotic coefficients and mean activity coefficients of 79 compounds are given together with the standard deviation, variance, and normalized standard deviation of their fit to equations which express these quantities as functions of electrolyte concentration. Finally, literature references are given to data on 51 additional uni‐univalent electrolytes.
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82.45.Gj Electrolytes

The Viscosity and Thermal Conductivity Coefficients of Gaseous and Liquid Fluorine

H. J. M. Hanley and R. Prydz

J. Phys. Chem. Ref. Data 1, 1101 (1972); http://dx.doi.org/10.1063/1.3253109 (14 pages) | Cited 1 time

Online Publication Date: 29 October 2009

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Tables of values for the viscosity and thermal conductivity of fluorine are presented in the range 70–300 K for pressures up to 200 atmospheres. Experimental results were reviewed but were judged to be unreliable. Accordingly, dilute gas values were determined from kinetic theory using the m‐6–8 potential, and dense gas and liquid values were obtained from the modified Enskog theory. The critical point anomaly in the thermal conductivity coefficient is also discussed.
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51.20.+d Viscosity, diffusion, and thermal conductivity
66.20.-d Viscosity of liquids; diffusive momentum transport
66.25.+g Thermal conduction in nonmetallic liquids
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